Search results for "Sulforhodamine 101"
showing 4 items of 4 documents
About the dynamics of strongly coupled surface plasmon polaritons and Sulforhodamine 101
2014
We investigate the dynamics of strongly coupled surface plasmon polaritons (SPP) and molecular excitations (ME) of Sulforhodamine 101 dye. The SPPs are excited by prism coupling technique on a thin silver film with dye molecules embedded in a polymer layer on top of it. Rabi splittings with energies of 135 and 97 meV are observed in the recorded dispersion relations. Both coupled oscillator model and transfer matrix method are used to fit the experimental results. In addition to the common reflectance measurements, polarization resolved detection of scattered signal from the molecular side is also utilized. Simultaneous detection of the scattered polaritons and molecular fluorescence reveal…
Azo-Sulforhodamine Dyes: A Novel Class of Broad Spectrum Dark Quenchers
2014
A rapid access to a novel class of water-soluble dark quencher dyes was achieved using an azo-coupling reaction between a fluorescent primary arylamine derived from a sulforhodamine 101 scaffold and a tertiary aniline equipped with different bioconjugatable groups. The thus obtained nonfluorescent azo-sulforhodamine hybrids display a broad quenching range spanning the visible to NIR regions. This was demonstrated through the preparation and enzymatic activation of FRET-based fluorogenic substrates of urokinase.
Surface plasmon polariton interaction with Sulforhodamine 101 dye
2011
The integration of conventional optical elements and electronic circuits is limited by size mismatch between these components. The diffraction limit does not allow miniaturizing optical elements to nm-scale. It was realized that light being strongly coupled to coherently oscillating electrons at the metal surface could be used to overcome this limit. The coupled state is called surface plasmon polariton. Surface plasmon polariton propagates in plane of metallic film within 10-100 μm range but decay exponentially in perpendicular directions to metal-dielectric boundary. Interaction of the surface plasmon polaritons with fluorescent dye molecules may result in development of new nanodimension…
Strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye
2011
We demonstrate a strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye molecules. Dispersion curves for surface plasmon polaritons on samples with a thin layer of silver covered with Sulforhodamine 101 molecules embedded in SU-8 polymer are obtained experimentally by reflectometry measurements and compared to the dispersion of samples without molecules. Clear Rabi splittings, with energies up to 360 and 190 meV, are observed at the positions of the dye absorption maxima. The split energies are dependent on the number of Sulforhodamine 101 molecules involved in the coupling process. Transfer matrix and coupled oscillator methods are used to model the studied multilaye…